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Polyfluorene

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Polyfluorene
Identifiers
CAS Number
Properties
Chemical formula (C13H10)x
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Polyfluorene (PFO) is a light-emitting polymer due to its electroluminescence.

The building block of the polymere is the fluorene unit. Polyfluorenes are electroactive and photoactive materials with exceptional electrooptical characteristics which are used for the production of light-emitting diodes. Polyfluorenes can emit colors over the whole visible range.

For polyfluorene the fluorene molecules are connected at the 2 and 7 positions

The first blue light emitting polymerdiode was produced with a substituted polyfluorene (poly(9,9-dihexylfluorene)).

An interesting use of Polyfluorene, together with lasers, provides a valuable explosives detection technology. Please see http://news.bbc.co.uk/1/hi/science_and_environment/10257425.stm for details.


References

  1. Mario Lecler (2001). "Polyfluorenes: Twenty years of progress". Journal of Polymer Science Part A: Polymer Chemistry. 39 (17): 2867–2873. doi:10.1002/pola.1266.
  2. Yutaka Ohmori, Masao Uchida, Keiro Muro and Katsumi Yoshino (1991). "Blue Electroluminescent Diodes Utilizing Poly(alkylfluorene)". Jpn. J. Appl. Phys. 30: L1941 – L1943. doi:10.1143/JJAP.30.L1941.{{cite journal}}: CS1 maint: multiple names: authors list (link)
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