Misplaced Pages

Cyclooctanone

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
Cyclooctanone
Identifiers
CAS Number
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.007.219 Edit this at Wikidata
EC Number
  • 207-940-2
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C8H14O/c9-8-6-4-2-1-3-5-7-8/h1-7H2Key: IIRFCWANHMSDCG-UHFFFAOYSA-N
SMILES
  • C1CCCC(=O)CCC1
Properties
Chemical formula C8H14O
Molar mass 126.199 g·mol
Appearance colorless solid
Density 0.956 g/cm
Melting point 29 °C (84 °F; 302 K)
Boiling point 86 12 torr
Refractive index (nD) 0.959
Hazards
GHS labelling:
Pictograms GHS05: CorrosiveGHS07: Exclamation mark
Signal word Danger
Hazard statements H315, H319, H335
Precautionary statements P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Cyclooctanone is an organic compound with the formula (CH2)7CO. It is a waxy white solid.

Synthesis and reactions

It can be prepared by

Among its many reactions, Baeyer-Villiger oxidation gives the nine-membered cyclic ester.

See also

References

  1. "Cyclooctanone". pubchem.ncbi.nlm.nih.gov.
  2. Dess, Daniel B.; Martin, J. C. (1991). "A useful 12-I-5 triacetoxyperiodinane (The Dess-Martin periodinane) for the selective oxidation of primary or secondary alcohols and a variety of related 12-I-5 species". Journal of the American Chemical Society. 113 (19): 7277–7287. doi:10.1021/ja00019a027.
  3. E. J. Eisenbraun (1965). "Cycloöctanone". Organic Syntheses. 45: 28. doi:10.15227/orgsyn.045.0028.
  4. Krow, Grant R. (1993). "TheBaeyer–VilligerOxidation of Ketones and Aldehydes". Organic Reactions. pp. 251–798. doi:10.1002/0471264180.or043.03. ISBN 978-0-471-26418-7.
Stub icon

This organic chemistry article is a stub. You can help Misplaced Pages by expanding it.

Categories: