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Hercynite

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Hercynite
General
CategoryOxide minerals
Spinel group
Spinel structural group
Formula
(repeating unit)
FeAl2O4
IMA symbolHc
Strunz classification4.BB.05
Crystal systemIsometric
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space groupFd3m (no. 227)
Identification
Formula mass173.81 g/mol
ColorBlack
Crystal habitEuhedral crystals. Also massive to granular
Cleavage indistinct
FractureUneven – flat surfaces (not cleavage) fractured in an uneven pattern.
Mohs scale hardness7.5
LusterVitreous (glassy)
Streakdark green
Specific gravity3.95
Optical propertiesIsotropic
Refractive indexn = 1.8
Other characteristicsnon-radioactive
References

Hercynite is a spinel mineral with the formula FeAl2O4.

It occurs in high-grade metamorphosed iron-rich argillaceous (clay-containing) sediments as well as in mafic and ultramafic igneous rocks. Due to its hardness it also is found in placers.

It was first described in 1847 and its name originates from the Latin name for the Harz, Silva Hercynia, where the species was first found.

Hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ferrous (Fe) ions and aluminium ions (Al); however some ferric ions (Fe) may be located in the structure of hercynite.

Melting point of this mineral is inbetween 1,692–1,767 °C (3,078–3,213 °F).

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Handbook of Mineralogy
  3. ^ Webmineral
  4. Mindat
  5. Jastrzębska, Ilona; Szczerba J.; Stoch P.; Błachowski A.; Ruebenbauer K.; Prorok R.; Snieżek E. (2015). "Crystal structure and Mössbauer study of FeAl2O4". Department of Ceramics and Refractories. Nukleonika-Journal of Nuclear Research. 60 (1). Institute of Nuclear Chemistry and Technology: 47–49. doi:10.1515/nuka-2015-0012.
  6. Agca, Can; Neuefeind, Jörg C.; McMurray, Jake W.; Weber, Richard; Navrotsky, Alexandra (2020-06-07). "Melting temperature measurement of refractory oxide ceramics as a function of oxygen fugacity using containerless methods". Journal of the American Ceramic Society. 103 (9): 4867–4875. doi:10.1111/jace.17216. ISSN 0002-7820. OSTI 1648884. S2CID 219429990.


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