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| Names | |
|---|---|
| Preferred IUPAC name 1-(4-Hydroxy-3-methoxy-5-nitrophenyl)ethan-1-one | |
| Other names
1-(4-hydroxy-3-methoxy-5-nitrophenyl)ethanone 4'-Hydroxy-3'-methoxy-5'-nitroacetophenone Nitroapocynin 5-Nitroapocynin | |
| Identifiers | |
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| Properties | |
| Chemical formula | C9H9NO5 |
| Molar mass | 211.173 g·mol |
| Appearance | Yellow powder |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references | |
Nitroapocynin is a mono-nitrated form of apocynin.
Synthesis
Apocynin can be nitrated with sodium nitrate and acidic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate in acetonitrile solvent.
References
- Tajik, H.; Niknam, K.; Parsa, F. (2009). "Using acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate in selective nitration of phenols under mild conditions". Journal of the Iranian Chemical Society. 6: 159–164. doi:10.1007/BF03246515. S2CID 55676239.
- Babu, Sainath; Raghavamenon, Achuthan C.; Fronczek, Frank R.; Uppu, Rao M. (2009). "4-Hydroxy-3-methoxy-5-nitroacetophenone (5-nitroapocynin)". Acta Crystallographica Section E. 65 (9): o2292-3. Bibcode:2009AcCrE..65o2292B. doi:10.1107/S160053680903390X. PMC 2969931. PMID 21577684.