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Tetramethylammonium auride

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Tetramethylammonium auride
Names
IUPAC name N,N,N-Trimethylmethanaminium auride
Identifiers
CAS Number
3D model (JSmol)
InChI
  • InChI=1S/C4H12N.Au/c1-5(2,3)4;/h1-4H3;/q+1;-1Key: FNABMZORGWEURW-UHFFFAOYSA-N
SMILES
  • C(C)(C)C.
Properties
Chemical formula C4H12AuN
Molar mass 271.114 g·mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Tetramethylammonium auride, (CH3)4NAu, is an ionic compound containing tetramethylammonium as cation and gold in a –1 oxidation state as anion. It is an example of a compound containing this rare ionic form of gold, and the first auride paired with a cation that is not a metal atom that has been synthesized.

References

  1. Dietzela, Pascal D. C.; Jansen, Martin (2001). "Synthesis and crystal structure determination of tetramethylammonium auride". Chemical Communications (21): 2208–2209. doi:10.1039/B105648B. PMID 12240114.

Further reading

Gold compounds
Gold(-I)
Gold(I)
Organogold(I) compounds
  • (AuC6H2(CH3)3)5
  • (C2H5)3PAuSC5H5O(CO2CH3)3CH2OCOCH3
  • AuSC5H5O(OH)3CH2OH
  • NaAuSCH2CHOHCH2SO3
  • BrAuSC4H8
  • ClAuSC4H8
  • ClAuS(CH3)2
  • ClAuP(C6H5)3
  • Na2AuSCHCO2CH2CO2
  • NaAuSCHCO2CH2CO2H
  • Gold(II)
    Gold(I,III)
    Gold(III)
    Aurates(III)
  • HAuCl4
  • NaAuCl4
  • HAuBr4
  • HAu(NO3)4
  • ClO2Au(ClO4)4
  • NaAuO2
  • Gold(V)
    Gold(VI)


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