Chemical compound
Trimolybdenum phosphide is a binary inorganic compound of molybdenum metal and phosphorus with the chemical formula Mo3 P.
Preparation
Trimolybdenum phosphide can be obtained via electrolysis of a melt mixture of molybdenum hexametaphosphate with molybdenum(VI) oxide and sodium chloride .
Properties
Trimolybdenum phosphide forms grey crystals of tetragonal crystal system with space group I4 . It is insoluble in water. Trimolybdenum phosphide becomes superconducting at 7 K.
Uses
Trimolybdenum phosphide can be used as a catalyst for electrocatalytic processes. It can also be used in accumulators.
References
Kondori, Alireza; Esmaeilirad, Mohammadreza; Baskin, Artem; Song, Boao; Wei, Jialiang; Chen, Wei; Segre, Carlo U.; Shahbazian-Yassar, Reza; Prendergast, David; Asadi, Mohammad (June 2019). "Identifying Catalytic Active Sites of Trimolybdenum Phosphide (Mo 3 P) for Electrochemical Hydrogen Evolution" . Advanced Energy Materials 9 (22). Bibcode :2019AdEnM...900516K . doi :10.1002/aenm.201900516 . ISSN 1614-6832 . OSTI 1531000 . S2CID 242323789 . Retrieved 9 March 2024.
Muchharla, Baleeswaraiah; Malali, Praveen; Daniel, Brenna; Kondori, Alireza; Asadi, Mohammad; Cao, Wei; Elsayed-Ali, Hani E.; Castro, Mickaël; Elahi, Mehran; Adedeji, Adetayo; Sadasivuni, Kishor Kumar; Maurya, Muni Raj; Kumar, Kapil; Karoui, Abdennaceur; Kumar, Bijandra (13 September 2021). "Tri-molybdenum phosphide (Mo3P) and multi-walled carbon nanotube junctions for volatile organic compounds (VOCs) detection" . Applied Physics Letters 119 (11). doi :10.1063/5.0059378 . S2CID 240537366 .
Donnay, Joseph Désiré Hubert (1973). Crystal Data: Inorganic compounds National Bureau of Standards . p. 16. Retrieved 9 March 2024.
Mellor, Joseph William (1971). Supplement to Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry: suppl. 1, pt. 1. N Longmans, Green and Company . p. 337. Retrieved 9 March 2024.
Kondori, Alireza; Esmaeilirad, Mohammadreza; Baskin, Artem; Song, Boao; Wei, Jialiang; Chen, Wei; Segre, Carlo U.; Shahbazian-Yassar, Reza; Prendergast, David; Asadi, Mohammad (June 2019). "Identifying Catalytic Active Sites of Trimolybdenum Phosphide (Mo 3 P) for Electrochemical Hydrogen Evolution" . Advanced Energy Materials 9 (22). Bibcode :2019AdEnM...900516K . doi :10.1002/aenm.201900516 . OSTI 1531000 . S2CID 242323789 . Retrieved 9 March 2024.
Kuei, Brooke (August 27, 2019). "Uncovering the Origin of High Performance in a New Water Splitting Catalyst" . foundry.lbl.gov. Retrieved 9 March 2024.
Timmer, John (6 February 2023). "New battery seems to offer it all: Lithium-metal/lithium-air electrodes" . Ars Technica
"(201d) First-Principles Study of Lithium-Air Batteries Based on Tri-Molybdenum Phosphide (Mo3P) Nanoparticles | AIChE" . aiche.org. Retrieved 9 March 2024.
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