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Grayite
General
Category	Phosphate minerals Rhabdophane group
Formula (repeating unit)	(Th,Pb,Ca)PO4·(H2O)
IMA symbol	Gry
Strunz classification	8.C.J.45
Dana classification	40.04.07.04
Crystal system	Hexagonal
Crystal class	Trapezohedral (622) (same H-M symbol)
Space group	P6222 or P6422
Unit cell	a = 6.957 c = 6.396 ; Z = 3
Identification
Color	Pale yellow, yellow, yellowish gray, often a dark reddish brown
Crystal habit	Cryptocrystalline Aggregate
Mohs scale hardness	3–4
Luster	Resinous to waxy to greasy
Diaphaneity	Semitransparent
Density	6.41 g/cm (calculated)
Optical properties	Uniaxial
Refractive index	nα = 1.66 nβ = 1.69
Birefringence	Moderate with max at δ = 1.660
Ultraviolet fluorescence	May fluoresce green or yellow under short wave UV
Other characteristics	Radioactive
References

Grayite, ThPO₄·(H₂O), is a thorium phosphate mineral of the Rabdophane group first discovered in 1957 by S.H.U. Bowie in Rhodesia. It is of moderate hardness occurring occasionally in aggregates of hexagonal crystals occasionally but more commonly in microgranular/cryptocrystalline masses. Due to its thorium content, grayite displays some radioactivity although it is only moderate and the mineral displays powder XRD peaks without any metamict-like effects. The color of grayite is most commonly observed as a light to dark reddish brown but has also been observed as lighter yellows with grayish tints. It has a low to moderate hardness with a Mohs hardness of 3–4 and has a specific gravity of 3.7–4.3. It has been found in both intrusive igneous and sedimentary environments.

Occurrence

Formations including grayite were originally documented in Rhodesia (now Zimbabwe) in 1957 and subsequently around the globe. Some of these locales include the states of Wyoming and Colorado as well as Madagascar. Grayite has often been found in pegmatitic environments amongst other thorium minerals, particularly monazite ((Ce,La)PO₄). Recent work has shown widespread occurrences in Wisconsin pegmatitic environments. Other notable finds of pegmatitic grayite occur in Bulgaria. Grayite has also been found in sedimentary environments with an observation of high concentrations in cracks raising the possibility of the mineral as a precipitate from fluid mobilized ions. Formation of grayite and other rhabdophane minerals in this context has been documented in literature.

As member of rhabdophane group

Grayite is isostructural with members of the Rhabdophane group such as brockite and rhabdrophane. While previous work has identified grayite as a pseudohexagonal orthorhombic member of the rhabdophane group along with ningyoite, more contemporary work seems to maintain a hexagonal crystal structure. These hydrated phosphate minerals often include radioactive elements such as thorium, uranium, and cerium. Powder XRD analysis produces peaks matching those of rhabdophane.

Relationship with monazite

In the identification of new hydrated phosphate minerals related to rhabdophane XRD peak information is usually recorded through different sample preparation methods. Besides standard powder XRD, samples are often heated to ~850 °C so that the structure changes. The peak information is analyzed again and upon doing this hydrated thorium phosphate minerals will show a monazite-like structure indicating a possible alteration relationship.

See also

• Classification of minerals
• List of minerals

References

1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
2. Grayite in Handbook of Mineralogy (PDF) . Retrieved on 17 November 2015.
3. Grayite at Mindat.org
5. ^
8. ^ J.R. Dooley, Jr., and John C. Hathaway, 1961, Two Occurrences of Thorium-bearing Minerals with Rhabdophane-like Structures, USGS Professional Paper 424-C, pg. 339–341

External links

• Thorium minerals
• Phosphate minerals
• Radioactive minerals
• Hexagonal minerals
• Minerals in space group 180 or 181
• Natural materials