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Silver oxalate

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Silver oxalate
Names
IUPAC name Silver(I) ethanedioate
Other names Silver Ethanedioate, Silver Salt
Argentous oxalate
Silver(I) oxalate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.791 Edit this at Wikidata
EC Number
  • 208-568-3
PubChem CID
RTECS number
  • RO2900000
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C2H2O4.2Ag/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2Key: XNGYKPINNDWGGF-UHFFFAOYSA-L
  • InChI=1/C2H2O4.2Ag/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2Key: XNGYKPINNDWGGF-NUQVWONBAW
SMILES
  • ..C(=O)C()=O
Properties
Chemical formula Ag
2C
2O
4
Molar mass 303.755 g/mol
Appearance white powder
Density 5.03 g/cm
Melting point 961.9 °C (1,763.4 °F; 1,235.0 K) (decomposes)
Boiling point 2,212 °C (4,014 °F; 2,485 K) at 1013.25 hPa
Solubility in water 3.270*10 g/100mL
Solubility product (Ksp) 5.4×10
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Harmful if swallowed
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒verify (what is  ?) Infobox references
Chemical compound

Silver oxalate (Ag
2C
2O
4)
is a silver salt of oxalic acid commonly employed in experimental petrology to add carbon dioxide (CO
2
) to experiments as it will break down to silver (Ag) and carbon dioxide under geologic conditions. It is also a precursor to the production of silver nanoparticles. It is explosive upon heating around 140 degrees Celsius, shock or friction.

Production

Silver oxalate is produced by the reaction between silver nitrate and oxalic acid.

See also

References

  1. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. Silver Oxalate at American Elements
  3. Silver Oxalate MSDS sheet Archived 2013-12-12 at the Wayback Machine at mpbio

External links

Silver compounds
Silver(0,I)
Silver(I)
Organosilver(I) compounds
  • AgC2H3O2
  • AgC22H43O2
  • CH3CH(OH)COOAg
  • C
    18H
    36AgO
    2
  • AgC4H3N2NSO2C6H4NH2
  • AgC
    11H
    23COO
  • Silver(II)
    Silver(III)
    Silver(I,III)
    Compounds of the oxalate ion
    (H2C2O4) He
    Li2C2O4 BeC2O4 +BO3 +CO3 (NH4)2C2O4
    +NO3
    O F Ne
    Na2C2O4
    NaHC2O4
    MgC2O4 Al Si +PO4
    +PO3
    +SO4 +Cl Ar
    K2C2O4
    KHC2O4
    CaC2O4 Sc Ti V CrC2O4 MnC2O4 FeC2O4
    Fe2(C2O4)3
    +Fe
    humboldtine
    +NH4 +Na +K +K
    CoC2O4 -Ni CuC2O4 Katsarosite Ga2(C2O4)3 Ge As Se Br Kr
    Rb2C2O4 SrC2O4 Y2(C2O4)3 Zr Nb(HC2O4)5 Mo Tc Ru Rh Pd Ag2C2O4 CdC2O4 In2(C2O4)3 SnC2O4 Sb Te I Xe
    Cs2C2O4 BaC2O4 * Lu2(C2O4)3 Hf Ta W Re Os Ir -Pt Au Hg Tl PbC2O4 Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La2(C2O4)3 Ce2(C2O4)3 Pr2(C2O4)3 Nd2(C2O4)3 Pm2(C2O4)3 Sm2(C2O4)3 Eu2(C2O4)3 Gd2(C2O4)3 Tb2(C2O4)3 Dy2(C2O4)3 Ho2(C2O4)3 Er2(C2O4)3 Tm2(C2O4)3 Yb2(C2O4)3
    ** Ac2(C2O4)3 Th(C2O4)2 Pa UO2C2O4 Np(C2O4)2 Pu(C2O4)2 Am Cm2(C2O4)3 Bk2(C2O4)3 Cf2(C2O4)3 Es2(C2O4)3 Fm Md No
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