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Sodium deuteroxide

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Sodium deuteroxide
Names
IUPAC name Sodium deuteroxide
Other names
  • Deuterated sodium hydroxide
  • Sodium hydroxide-d
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.373 Edit this at Wikidata
EC Number
  • 237-825-2
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Na.H2O/h;1H2/q+1;/p-1/i/hDKey: HEMHJVSKTPXQMS-DYCDLGHISA-M
SMILES
  • .
Properties
Chemical formula NaOD or NaOH
Molar mass 41.003 g/mol
Appearance White solid
Solubility in water Soluble
Hazards
GHS labelling:
Pictograms GHS05: Corrosive
Signal word Danger
Hazard statements H290, H314
Precautionary statements P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3 0 1
Related compounds
Related compounds Sodium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Sodium deuteroxide or deuterated sodium hydroxide is a chemical compound with the formula NaOD or NaOH. IUPAC recommends that the symbol for deuterium should be H, although most chemists use the term NaOD. It is a white solid very similar to sodium hydroxide, of which it is an isotopologue. It is used as a strong base and deuterium source in the production of other deuterated compounds. For example, reaction with chloral hydrate gives deuterated chloroform, and reaction with N-nitrosodimethylamine gives the deuterated analog of that compound. Sodium deuteroxide is an ionic compound, consisting of sodium cations Na and deuteroxide anions OD (or OH).

Notes

References

  1. "Sodium deuteroxide". Sigma aldrich. Retrieved 30 April 2021.
  2. "Provisional Recommendations". Nomenclature of Inorganic Chemistry. Chemical Nomenclature and Structure Representation Division. IUPAC. § IR-3.3.2. Archived from the original on 27 October 2006. Retrieved 2024-08-01.
  3. Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)". Journal of the American Chemical Society. 57 (11): 2236–2237. doi:10.1021/ja01314a058.
  4. National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.
Sodium compounds
Inorganic
Halides
Chalcogenides
Pnictogenides
Oxyhalides
Oxychalcogenides
Oxypnictogenides
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Organic
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