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Sodium hypoiodite

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Sodium hypoiodite
Names
IUPAC name Sodium hypoiodite
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/IO.Na/c1-2;/q-1;+1Key: SAFWHKYSCUAGHQ-UHFFFAOYSA-N
SMILES
  • I.
Properties
Chemical formula INaO
Molar mass 165.893 g·mol
Related compounds
Other anions
Other cations Silver hypoiodite
Related compounds Hypoiodous acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Sodium hypoiodite is an inorganic chemical used as an oxidant in various organic chemical reactions. It causes iodination of nitrogen atoms, such 1H-benzotriazole to give 1-iodo-1H-benzotriazole and an imine to give the analogous iodoimine. It oxidatively cleaves methyl ketones to give iodoform.

References

  1. Kambe, N., ed. (2008). "Product Class 4: Acyclic Dialkyl Sulfoxides and Derivatives". Category 5, Compounds with One Saturated Carbon Heteroatom Bond. doi:10.1055/sos-SD-039-00359. ISBN 978-3-13-118921-9.
  2. Gatenbeck, S.; Bentley, R. (1965). "Naphthaquinone Biosynthesis in Moulds: The Mechanism for Formation of Javanicin". Biochemical Journal. 94 (2): 478–481. doi:10.1042/bj0940478. PMC 1206531. PMID 14348208.
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Sodium compounds
Inorganic
Halides
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Pnictogenides
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